The ability to fix the FWHM (Full Width at Half Maximum) or the area ratio (e.g., the 2p3/2 and 2p1/2 doublet ratio).
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No matter which software you download, your analysis is only as good as your reference data. Always cross-reference your binding energy shifts with the NIST X-ray Photoelectron Spectroscopy Database. The ability to fix the FWHM (Full Width
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